PVA is an atactic material that exhibits crystallinity. In terms of microstructure, it is composed mainly of 1,3-diol linkages [-CH2-CH(OH)-CH2-CH(OH)-] but a few percent of 1,2-diols [-CH2-CH(OH)-CH(OH)-CH2-] occur, depending on the conditions for the polymerization of the vinyl ester precursor.

PVA is usually processed in the form of aqueous solution. Since the solution is slightly acidic (pH 5~7), vessel should be made of materials, which will not contaminate the solution with corrosive material or rusts. Stainless steel vessel, enameled containers or polyester tanks are recommended.